DEEP OXDATION OF CHLORINE-CONTAINING ALKANES IN HETEROGENEOUS OXIDE CATALYSTS

Nanostructured Catalysts in Activation of Light Alkanes

The activation of small alkane molecules originating from natural gas or renewable resources on metal oxide surfaces regains increasing scientific interest since direct utilization of saturated hydrocarbons will offer alternative pathways to higher value chemicals in a postpetroleum era. The focus of the project lies on oxidation catalysis of small alkane molecules including methane, ethane, pr...

comparison of catalytic activity of heteropoly compounds in the synthesis of bis(indolyl)alkanes.

heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...

Modeling heterogeneous catalysts: metal clusters on planar oxide supports

Model catalysts consisting of Au and Ag clusters of varying size have been prepared on single crystal TiO2(110) and ultra-thin films of TiO2, SiO2 and Al2O3. The morphology, electronic structure, and catalytic properties of these Au and Ag clusters have been investigated using low-energy ion scattering spectroscopy (LEIS), temperature-programmed desorption (TPD), X-ray photoelectron spectroscop...

Photochemical ozone and nitric oxide formation in air--nitrogen dioxide mixtures containing sulfur dioxide or chlorine.

Experiments were performed to investigate the effects of sulfur dioxide (O-10 ppm) and chlorine (O-15 ppm) on ozone and nitric oxide concentrations in irradiated mixtures of nitrogen dioxide (1-5 ppm) and air. The mixtures were irradiated by ultraviolet fluorescent lamps while flowing at a steady speed through a 9 m long, 15.2 cm i.d. Pyrex tube. The presence of sulfur dioxide produced no measu...

Dehydrogenation by Heterogeneous Catalysts